1.4477 is a high-chromium, low-molybdenum super duplex stainless steel , with a microstructure of roughly equal ferrite and austenite. This datasheet presents the material within the European standard system.
The EN designation 1.4477 indicates approximately 29% chromium, 7% nickel and 2% molybdenum, with a high nitrogen addition. Compared with the 2507-type super duplex 1.4410 (25Cr-7Ni-4Mo), 1.4477 substitutes higher chromium and nitrogen for part of the molybdenum, giving a high PREN with good resistance to chloride pitting and stress-corrosion cracking, while improving resistance in certain acidic/abrasive media. It must not be confused with the 4%-molybdenum grade 1.4410; the chemistries are different (29Cr-2Mo versus 25Cr-4Mo).
Typical applications include seawater and brackish-water systems, umbilical and hydraulic tubing, oil-and-gas equipment, and process equipment requiring high strength with high-chloride corrosion resistance.
| Property | Value | Unit |
|---|---|---|
| Density | 7.8 | g/cm³ |
| Melting range | 1350-1400 | °C |
| Young's modulus (20 °C) | 200 | GPa |
| Thermal conductivity (20 °C) | 15 | W/m·K |
| Coefficient of thermal expansion (20-100 °C) | 13 | µm/m·°C |
| Specific heat (20 °C) | 480 | J/kg·K |
| Magnetic response | Ferromagnetic (duplex) | — |
| Element | Symbol | Min % | Max % | Role in Alloy |
|---|---|---|---|---|
| Iron | Fe | Balance | — | Base element |
| Chromium | Cr | 28.0 | 30.0 | Ferrite former; corrosion resistance |
| Nickel | Ni | 5.8 | 7.5 | Austenite former; phase balance |
| Molybdenum | Mo | 1.5 | 2.6 | Pitting + crevice resistance |
| Nitrogen | N | 0.30 | 0.40 | Austenite former; strength; pitting |
| Manganese | Mn | 0.80 | 1.50 | Deoxidiser; N solubility |
| Silicon | Si | — | 0.50 | Deoxidiser |
| Carbon | C | — | 0.030 | Low (intergranular resistance) |
| Phosphorus | P | — | 0.030 | Residual impurity |
| Sulphur | S | — | 0.015 | Residual impurity |
Solution-annealed (+AT) condition, per EN 10088-3 for W.Nr. 1.4477.
| Property | Value | Unit |
|---|---|---|
| Tensile strength (Rm) | 750-1000 | MPa |
| 0.2% proof strength (Rp0.2) | >=550 | MPa |
| Elongation at fracture | >=25 | % |
| Impact energy (KV, +20 °C) | >=100 | J |
| Brinell hardness | <=290 | HB |
Values per EN 10088-3. Confirm against the inspection certificate (EN 10204).
| Environment | Performance | Notes |
|---|---|---|
| Chloride pitting | Outstanding | High Cr + N |
| Crevice corrosion | Outstanding | High-Cr duplex |
| Chloride SCC | Excellent | Duplex structure |
| Seawater | Excellent | Warm chlorinated seawater |
| General (oxidizing) | Excellent | Very high chromium |
| Intergranular (welded) | Resistant | Low carbon |
The high-chromium chemistry gives excellent localized-corrosion resistance, comparable to the 2507 family with a different alloying balance.
Not hardenable by heat treatment; properties are set by solution annealing and phase balance.
Solution Anneal approximately 1040-1120 °C, followed by rapid water quench to retain the balanced ferrite-austenite structure. Rapid cooling is critical owing to the high alloy content. Avoid prolonged exposure in the 300-1000 °C range (sigma-phase / 475 °C embrittlement).
Weldable by common fusion methods with a matching or over-alloyed super-duplex filler and controlled heat input to maintain phase balance.
| Process | Applicability | Filler / Consumable |
|---|---|---|
| GTAW / TIG | Good | Over-alloyed super-duplex filler |
| GMAW / MIG | Good | Super-duplex filler |
| SMAW / stick | Good | Matching super-duplex electrode |
No preheat; control interpass temperature and heat input; resistant to intergranular corrosion in the as-welded condition owing to the low carbon.
Machining Guidelines
| Parameter | Recommendation |
|---|---|
| Machinability | Difficult; high strength + work-hardening; rigid setup, carbide tools, low speeds |
| Work hardening | High rate; positive feeds, avoid dwelling |
| Coolant | Ample flood coolant |
Forming Processes
| Process | Notes |
|---|---|
| Hot forming | ~1230-1000 °C; solution anneal + quench afterward |
| Cold forming | Higher forces than 1.4462 (very high strength) |
| Industry | Typical Components | Key Requirements |
|---|---|---|
| Marine / seawater | Seawater systems, umbilical tubing | Warm chloride resistance |
| Oil & gas | Hydraulic / umbilical tubing, components | Pitting + sour-service resistance |
| Desalination | Heat exchangers, piping | Hot chloride resistance |
| Chemical processing | Vessels, piping | Localized-corrosion resistance |
| Product Form | Standard | Notes |
|---|---|---|
| Plate, sheet and strip | EN 10088-2 · W.Nr. 1.4477 | X2CrNiMoN29-7-2 |
| Bar, rod, wire and sections | EN 10088-3 / EN 10088-5 · W.Nr. 1.4477 | — |
| Seamless tube | EN 10216-5 / EN 10297-2 · W.Nr. 1.4477 | — |
| Sour service | ISO 15156-3 | Acid-gas applications |
High-chromium super duplex stainless steel. W.Nr. 1.4477; EN 10088-3.
| W.Nr. | Cr % | Ni % | Mo % | N % | Best Used For |
|---|---|---|---|---|---|
| 1.4477 | 28-30 | 5.8-7.5 | 1.5-2.6 | 0.30-0.40 | High-Cr super duplex (low Mo) |
| 1.4410 | 24-26 | 6.0-8.0 | 3.0-4.5 | 0.24-0.35 | 2507 super duplex (high Mo) |
| 1.4501 | 24-26 | 6.0-8.0 | 3.0-4.0 | 0.20-0.30 | Super duplex with W + Cu |
| 1.4462 | 21-23 | 4.5-6.5 | 2.5-3.5 | 0.10-0.22 | Standard duplex |
| 1.4404 | 16.5-18.5 | 10-13 | 2.0-2.5 | — | Austenitic general service |




